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Permeability

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Permeability describes the transmission of a medium, most likely of a gas, rather seldom of a liquid, through a test specimen. The permeability process can be divided into three separate steps:

• Entrance of the medium into the test specimen

• Diffusion of the medium through the test specimen

• Escape of the medium from the test specimen

The permeability is directly proportional to the temperature and inversely proportional to the wall thickness.

Gas Permeability

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The following table shows the gas permeability of different gases at some important Desmopan – grades measured to DIN 53380, Part 1 at films of 100 µm thickness.

Desmopan 385

Desmopan 385

Desmopan 786

Desmopan 786

Desmopan 9385

Desmopan 9385

Gases

25°C

60°C

25°C

60°C

25°C

60°C

Air

450

1000

600

3500

N2

330

1800

500

3600

500

2800

O2

840

4500

1500

8000

2000

9400

CO2

6500

19000

8400

27000

6000

28000

He

2600

9700

4500

16000

4600

16500

Propane

2400

4000

18000

Natural Gas

1000

N2O

12400

14000


Thermoplastic polyurethanes are normally not used as barrier materials. But polyester – TPU tends to have a lower gas permeability compared to polyether – TPU. Hence they are more suitable as a barrier material.

For a further reduction in gas permeability, additives are known, and can be compounded into the material, which will reduce the gas permeability by about 30 %.

If high gas permeability is requested, either polyether – TPU or the special polycarbonate – TPU are more suitable. The later ones are especially interesting, if the higher gas permeability is required in combination with a good chemical resistance against a wider range of substances.

Fuel Permeability

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The following table shows the fuel permeability (FD) of Desmopan 786. The measurement was done according to DIN 53532 on a polyester fabric coated on both sides with a layer of 100 µm of Desmopan 786.

Fuel 1

Fuel 2

Fuel 3

FD (g / m² x d)

FD (g / m² x d)

FD (g / m² x d)

8

280

2600


Fuel 1 = isooctane (2,2,4 – trimethylpentane)
Fuel 2 = isooctane / toluene (70 : 30 Vol.%)
Fuel FAM = pure toluene / isooctan / diisobutylen / pure ethanol (50:30:15:5 Vol.%)

Desmopan 786 is a polyether – carbonat – TPU especially suitable for the contact with fuel and water at the same time.

Due to the unique formulation of Desmopan 786, it has an equally high resistance against fuels and hydrolysis.